Aluminum is the easiest metal to work with I find. Mineral stains and other difficult chemical stains can be a pain to remove unless you have a few minutes with some sandpaper and polish. What I use, depending on how bad the stain is (eg.. excessive oxidizing from purple degreaser ).. for that I would start with 800 grit untill I barely see a spot. then move to 1000 for just a minute or two, then 1500, then 2000. With the 2000, I keep sanding until the sandpaper gets a bit clogged with metal particles. I then lighten the hand pressure and go over it with the clogged (NON -Wet) sandpaper. 2000 grit sandpaper worn down a bit and clogged with aluminum particles turns it into an almost 2500 - 3000 grit material which buffs the surface to an even deeper mirror finish. This must be done right otherwise you'll just re-deposit aluminum particles into the finish and haze it up. After this, I follow up with MAAS polishing creme. If you haven't heard of MAAS, check out
MAAS . I have been using their metal polishing creme for 10 years. It's the best stuff out I think. Way better than Mothers Mag wheel polish or Meguires ...don't think Brasso will do any good, cause it wont. Take my word, I've been re-finishing metals for years.
Now you may not want to go with the 800 grit. That seems a bit rough for just antifreeze. Can you show me a picture of the coolant stain on the valve cover?