Is your engine built to specifically use high octane?
If not, you are hurting your mileage, power, and longevity using too much octane.
The fuel companies want you to think higher octane is some magical formula that gives you more power, economy, and even cleans your engine, but it doesn't. That is all marketing.
Octane rating is a rating of the fuel's volatility.
Higher octane is harder to ignite and burns slower.
That is required in some high pressure (boosted) or high compression engines, to prevent piston meltdown, or preignition (combustion timing issues).
However, when used in your average street engine, the fuel does not burn completely, wasting it, losing potential power, and crudding up your engine/exhaust/cats.
Just a heads up.
Use the lowest possible octane you can use without detonation/preignition.