Does nitrous have a shelf life?

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It will be patiently waiting to do its job.

I've had a full bottle in a 100* day inside the car... PSI got high, like 1600-1700psi but the blowoff is set at 3000psi I think. Once you use some, it'll hit 14-1500psi if the car is sitting in the sun long enough. So far no problems though.