It's a bit more complex than just the number of cats. Back in the day they had 1-way and 2-way cats. There are 3 emissions components that are controlled - unburned hydrocarbons (HC), carbon monoxide (CO), and oxides of nitrogen (NOx). A 2-way cat catalyzes chemical reactions in the exhaust stream that clean up 2 of the 3 controlled emissions, a 1-way cat catalyzes reactions that clean up the other one. The older cars had 4 cats - on each side there was one 1-way cat and 1 2-way cat in order to clean up all 3 emissions. In later years they developed 3-way cats - a single cat that cleaned up all 3 emissions - V-8 cars with duals equipped with 3-way cats had just one cat per side. So, if you just have to pass the sniffer - a single 3-way cat on each side should do the job. If PA is gonna insist that you have the same number of cats on the car that it came with from the factory, then you need to be certain you have the right type of cats on the car. So you see - you can't just throw any 4 cats on the car - the right type have to be on there to control the emissions.