higher octane, car runs better?

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Stock 5.0 HO compression is 9.2:1, 87 octane is plenty for this, octane is simply for detonation, the quality of the fuel should be the same. It is possible that where you buy gas from has crappy 87 quality, and higher 92 quality. Which, is odd, since the longer a fuel sits, the worse it burns.. and one would assume higher octanes, being less sought after, would be more prone to degredation.