I have a highly modified 5.0 with a paxton novi 2k. I recently got 25 MPG on the highway. The supercharger wont hurt mileage at all if you keep you foot out of it. In fact, it can help because it will increase your low end torque allowing you to drive the car at highway speed at low RPM's. But this is assuming your doing highway speeds and once again, keeping your foot out of it.
The flip side is, once you have a supercharger, its easy to get crazy and feel the power and gun it all around town... of course if you do this, you will get ****ty gas mileage. Or in your case- ****tier! Good luck