well I hate to say this but you have bigger problems than that.. I am going to lay out some of the issues I see from quickly glancing through the tune file, most of these are simply novice mistakes and can be corrected easily.
your final row [value] in the warmup enrichments is set to 125.. this means that even fully warm you are adding 25% of your fuel from this modifier table. This explains the unrealistic values in the VE table.
your req fuel value is half of what it should be, this means you changed something major at some point and did not recalculate or you input the value by hand to compensate for the incorrect warmup enrichment.
as for the car dying on startup, I cannot see what the AFR is because the wideband has not started reading yet. but I will assume based on the condition of the tune it is fuel related.