Short answer, because the 4v flows more air, which equals more HP.
Long answer: This is right out of the book.
The 4v engine does not require as much valve lift to achieve high flow rates, because the valve curtain area of the valve is the limiting factor to flow. The curtain area of a 4v design is much larger at lower vale lifts than a similar 2v design. A single intake valve would require a valve lift of .821 inches to match the valve curtain area of the 2 smaller intake valves in a 4v design with only .500 inches of lift.
Valve curtain area comparison:
4 valve head with two 37MM diameter intake valves with .500 inch of lift equals a valve curtain area of 4.57 square inches.
2 valve head with one 45MM diameter intake valve with .821 inch of lift equals a valve curtain area of 4.57 square inches.
This is the advantage a 4v head has over a 2v. To achieve over .800 inches of lift on a 2v design requires some very exotic valvetrain components, where achieving a similar flow potential with a 4v head can be achieved using mostly production pieces.