no fuel can make you pass, but running the appropriate fuel will help your car to run properly. that is, DO NOT run premium fuel on a stock mustang, it's a waste of $, fuel, and it will pollute the environment. if your car runs on 87octane without detonation that is what you should run. when running higher octane than required the fuel doesn't burn completely which in turn screws the emissions.
other things to note: do a complete tune up to your spark system and drive the bags off your car to heat the cats up nicely immediately before you strap her down for the test.
i don't recommend adding anything to your fuel. if your car is running right it will pass, if it doesn't pass, it needs a tune anyway.
cool?
-steve